Mercury also combines with carbon to make organic mercury compounds. Ohio Admin. Use the shipping name and its corresponding data (UN number, class, packing group/category) in Schedule 1 to assign the classification to the dangerous good. If you are a consultant, you may get yourself listed in CSP business directory (free) or WebMercury (Metallic) Quicksilver; Hydrargyrum; Liquid Silver 1.2. Initial boiling point is greater than 35C at an absolute pressure of 101.3 kPa. ), MARINE POLLUTANT. ; UN 1992, FLAMMABLE LIQUID, TOXIC, N.O.S. CCOHS is not liable for any loss, claim, or demand arising directly or indirectly from any use or reliance upon the information. UN 3506: Mercury contained in manufactured articles - Substance Regulatory information United States of America Inventory Component CAS-No TSCA TSCA Inventory notification - Active/Inactive TSCA - EPA Regulatory Flags Mercury The Some manufacturing is in Fond du Lac, while 40-60 HP motors are made in China. A proof of classification is a document that the consignor must provide, upon request, to the federal Minister of Transport. See Section 4.23 of Part 4 in the TDG Regulations. You need to choose a UN number (usually, 4 digits) and a proper shipping name from Dangerous Goods List that can most accurately describe your dangerous goods. How does the consignor determine the classification for a dangerous good? Figure 3: Placard requirement and placement for a single dangerous good transported in a highway tank Image from Transport Canada. Classes The subsidiary hazard class or division number is not required to be entered when a corresponding subsidiary hazard label is not required. ), 3. Note 4: As the dangerous good is not identified with UN3373, the Category B mark is not required. (i) The words Class or Division may be included preceding the primary and subsidiary hazard class or division numbers. Are there any exemptions for placards? This mark is required when shipments meet the limited quantity exemption, and must be displayed on one side of a means of containment. The concentration of the solution or mixture may be included. For more details, consult the legislation directly. Always checkwith Transport Canada andtheTDG Act and Regulationstoensure compliance. The compatibility group is only assigned for explosives. This mark is displayed on small means of containment filled with infectious substances that are assigned to UN3373, Biological Substance Category B. Placard for the subsidiary hazard class (if any) next to the primary hazard class placard on each side and each end (total of four) for: Each dangerous good that must have an ERAP. For example: Which labels or placard that must be displayed depend on the classification of the dangerous good. Please also see the following documents in this series: The consignor is responsible for determining the classification of dangerous goods. Safety Data Sheet Mercury (Metallic) - WMSolutions.com The ICAO Technical Instructions, as well as Part 12, Air, of the TDG Regulations must be consulted for all shipments by air. Note: A mixture or solution that is not mentioned in the Dangerous Goods List and that is composed of two or more dangerous goods shall be assigned one entry that most precisely describes the solution or mixture. 1273 0 obj <> endobj See Section 4.10(5) in the TDG Regulations for circumstances when labels are not required and the "Packaging and Transport of Nuclear Substances Regulations" for specific marking requirements. Basic Information about Mercury Subscribe to Free Newsletter Other requirements may be listed in other sections, regulations, Codes, or Acts that are not listed in this table. The picture below shows hazard symbols for Class 4 dangerous goods. Abbreviations may be used for indicating packaging types (for example, cyl. for cylinder) provided the abbreviations are commonly accepted and recognizable. As Marine Pollutants Only: sponsor this page to leave your contact info on this page.. Proper shipping name is the standard technical name to describethe hazard properties and the composition of dangerous goods. The material's flash point will be displayed with the unit of measure and followed by "c.c." Dangerous goods in large means of containment (greater than 450 L) that are transported at: This sign must be displayed on each side and on each end of the large means of containment (i.e., total of 4 signs) next to each primary class placard for the dangerous goods or, if there is a subsidiary class placard, next to the subsidiary class placard. It exists in several forms: Elemental (metallic) mercury. I, II or III) assigned to the substance or article. For pure chemical substances or well-defined articles, it is easy to choose UN numbers and proper shipping names. For example: UN3086, TOXIC SOLID, OXIDIZING, N.O.S. Where can I get my product analyzed for classification? Specific chemical name (e.g., acetone, sulfuric acid, etc. Transportation of Dangerous Goods (TDG (b) for a liquefied petroleum gas that has not been odorized, the words Not Odourized or Not Odorized or Sans odorisant. For most of dangerous goods, the primary class and subsidary class can be found in Dangerous Goods List. Browse our full range of workplace health and safety products and services. size of the means of containment (e.g., small vs. large). Hazard class (the primary class and possible subsidiary class/es), Packing group, compatibility group, or the infectious substance category for biohazardous substances, SHIPPING NAME (in Column 2 of Schedule 1): GASOLINE; MOTOR SPIRIT; or PETROL (when selecting the shipping name you can use one of the three listed names such as gasoline), Hazard Class (in Column 3 of Schedule 1): 3, Identification Number (in Column 1 of Schedule 1): UN1203, Packing Group (in Column 4 of Schedule 1): II, UN1096 SIGNALS, SMOKE which is not allowed to be transported on a ship. Mercury. If two or more dangerous goods have different UN numbers but are identified by the same placard or placards, the placard is required to be displayed only once on each side and on each end of a large means of containment regardless of how many products in the large means of containment have that class (primary or subsidiary) [See Section 4.15 in the TDG Regulations]. hb```~ !o2)r10Dj`{0j@qz}]1%8Lt29+@b`t/c 9/fiF ~` C# Webmercury and mercury compounds: 0.1 mg/m3 (TWA), skin - ACGIH Threshold Limit Value (TLV): inorganic and metallic mercury, as Hg: 0.025 mg/m3 (TWA) skin, A4 Not Oxidizing 6. See Section 1.17 in the TDG Regulations. UN Dangerous Goods List If the product is not listed by specific name in Schedule 1 or 3, check if it meets any of the criteria for the hazard classes in Part 2 - Classification. Which words shall be added depend on the hazard, composition, state of the dangerous goods and the mode of transport. (vii) For hazardous materials in limited quantities, the total net quantity per package must be shown unless a gross mass is indicated in Column 4 of 173.27 Table 3, in which case the total gross mass per package must be shown. Examples: COTTON WASTE, OILY (UN1364), or REGULATED MEDICAL WASTE, N.O.S. hbbd``b`$@@YD$;! Image from Alberta EDGE (Environmental and Dangerous Goods Emergencies), Alberta Transportation. The size (i.e., capacity) of the means of containment itself also determines whether a label or placard is required. Determine the primary class, subsidiary class(es) and packing group by using section 2.8 - Precedence of Classes in Part 2, Classification. Consult Schedule 3 for the shipping name that most precisely describes the dangerous goods. Some of the classes can be further divided into divisions, e.g., Class 1, while others do not have sub-divisions, e.g., Class 3. as appropriate. Note 2: Package certification safety marks are specified in the standard that the package or container is compliant with. For example: UN1993, FLAMMABLE LIQUID, N.O.S. If the product's name (e.g., chemical name) is listed in Schedule 1 or 3, the primary hazard class is listed in Column 3 of Schedule 1 as well as in Column 2 of Schedule 3 for that shipping name. Where or how do I find the above information? %PDF-1.4 Class 2.1 Dangerous Goods For the dangerous goods other than Class 1 DG, a Conveyance Permit (For Dangerous Goods other than Class 1 Dangerous Goods) is required. The subsidiary class is the other class that further identifies the hazards of the dangerous goods. See Section 4.16(2) of Part 4 in the TDG Regulations. Code 3701:1-50-23 - 3701:1-50-23 - Advance notification of shipment of irradiated reactor fuel and nuclear waste. For example, if you have a product for which you determined that the shipping name will be FLAMMABLE LIQUID, N.O.S. ), code or number for a particular hazard (e.g., 1- Explosive, 2 - Gases, 3 - Flammables), Provide quick identification of the dangerous goods in an emergency (e.g., release of dangerous goods during an incident), Communicate the nature and degree of the danger, Quickly determine if dangerous goods in a mixed load are incompatible, is determined to be a dangerous good under the TDG Regulations, and, displayed against a background of contrasting colour, made of durable, weather-resistant material that will resist coming detached or fade, Select the correct label(s) for each small means of containment (e.g., drum, package, overpack), Make sure that each small means of containment (e.g., package or container) of dangerous goods is properly labelled and marked, Select the correct placards and other safety marks for each large means of containment (e.g., tanker), Display the placards and other safety marks, or provide the appropriate placards to the carrier (when the means of containment or means of transport belongs to the carrier), Confirm that the safety marks are correct, Make sure the safety marks are displayed and remain displayed during transport, Replace safety marks when during transport they are stolen, lost, or defaced, Provide and display appropriate safety marks when the contents of the shipment change (e.g., new consignments are loaded on the means of transport), Remove or cover safety marks when the dangerous good is no longer present. These criteria are outlined in the TDG Regulations. (ii) The hazard class need not be included for the entry Combustible liquid, n.o.s.. WebThe subsidiary hazard class or division number is not required to be entered when a corresponding subsidiary hazard label is not required. Read More: Marine Pollutants & Environmentally Hazardous Substances: Definition, Marking and Exceptions. `9yYcQKL U\ >5Iy+&1fXM+DD.> vl=|TOZg]-L8o1016&nY#Xh*4z5tGLUlWi. (iv) for dangerous goods with a primary class of Class 1, Explosives, the compatibility group letter following the primary class. (iii) The following are excepted from the requirements of paragraph (a)(5) of this section: (A) Bulk packages, provided some indication of the total quantity is shown, for example, 1 cargo tank or 2 IBCs., (B) Cylinders, provided some indication of the total quantity is shown, for example, 10 cylinders.. See Section 2.5. Code tit. However, the mixture could no longer be described as "Gasoline" or "Diesel" since it would no longer have a specific name in Schedule 1. Rules 007-001-RH-3509 - RH-3509 - Advance Notification of Shipment of Irradiated Reactor Fuel and Nuclear Waste. Radioactive 8. If you use UN 3077 or UN 3082, the proper shipping name shall also be supplemented with technical names. It exists in three forms that have different properties, usage, and toxicity. If the product's name (e.g., chemical name) is listed in Schedule 1 or 3 then the primary hazard class is in Column 3 of Schedule 1 and in Column 2 of Schedule 3 for that shipping name. Powdered metals. Have the answers at your fingertips. 120.790 - 120.790 - Advance Notification of Shipment of Nuclear Waste, 180 Neb. The rules are set out in a table, the segregation table in 7.2.4, and also have to be applied in respect of any subsidiary class. NOTE: The table below is for guidance purposes only. What is its predominant hazard substance and primary hazard? Who is responsible for classifying a dangerous good? 157.94 - DHS 157.94 - Operating controls and procedures. For hazardous mixtures or other articles, it takes more efforts and expertise to determine an accurate UN number and proper shipping name. UN-2 The type of packaging and destination marks may be entered in any appropriate manner before or after the basic description. Products and (UN3291). Scheduled maintenance - Thursday, July 12 at 5:00 PM Inorganic mercury compounds. The primary class is the class of dangerous goods that takes precedence over any other class. Dangerous Goods Safety Marks - Transport Canada (viii) For authorized consumer commodities, the information provided may be either the gross mass of each package or the average gross mass of the packages. Not required to be displayed on road vehicles. NOTE: See further belowin the table for placard requirement when the hazard class is 1.1, 1.2, 1.3, 1.4 or 1.5 are above a certain threshold of gross mass/number of articles. Select country for which that subsidiary belongs to. For detailed information, please see Part 2 of TDG Regulations. stream (a) The shipping description of a hazardous material on the shipping paper must include: (1) The identification number prescribed for the material as shown in Column (4) of the 172.101 table; (2) The proper shipping name prescribed for the material in Column (2) of the 172.101 table; (3) The hazard class or division number prescribed for the material, as shown in Column (3) of the 172.101 table. [1] if applicable, the classification method used under Part 2 of the TDG Regulations or under Chapter 2 of the UN Recommendations. More than one subsidiary class is possible. Trade name is not accepted. Code DHS Sec. Mercury is a naturally occurring trace metalloid element and known neurotoxin with atomic symbol Hg, atomic number 80, and atomic weight 200.59. From the surface of Mercury, the Sun would appear more than three times as large as it does when viewed from Earth, and the sunlight would be as much as seven times brighter. For articles (e.g., UN2800 and UN3166) the quantity must be the gross mass, followed by the letter G; and. Note that the TDG Directorate has not examined or certified any of the laboratories. We expect this update to take about an hour. White asbestos (chrysotile, actinolite, anthophyllite, tremolite), Dangerous Goods of Class9, Packing Group III, Liquids, not listed above, Dangerous Goods of Class9, Packing GroupIII, Solids, not listed above. 12 Va. Admin. 1 0 obj It is determined according to the specification in section 2.8 and the Precedence of Classes Table which is provided in Part 2. Environmentally hazardous substance, solid, n.o.s. The class posing a lower hazard will be identified as a subsidiary class. The metal is obtained by heating cinnabar in a current of air and condensing the vapour. Column 5 Packing Group Contains the packing group number (i.e. Mercury Marine Safety data sheet SECTION 1: Identification of the Mercury Factsheet | National Biomonitoring Program | CDC If a substance is included in more than one class or packing group, its classification is determined in the following manner: 33, Part XV, 1519 - 1519 - Advance Notification of Shipment of Irradiated Reactor Fuel and Nuclear Waste [Formerly 1516], 10 144 Me. Self-heating solid, corrosive, organic, n.o.s. Packing Group This column gives the packing groups of the dangerous goods. When are dangerous goods safety marks required? Wis. Admin. The smallest planet in our solar system and nearest to the Sun, Mercury is only slightly larger than Earth's Moon. When shipping marine pollutants by sea, the proper shipping name shall be be supplemented with the technical name of the marine pollutant. Can I use a UN number that is not included in the Canadian TDG Regulations? Class1.1, 1.2, 1.3 or 1.5 explosives that are: not subject to Special Provision 85 or 86 and the quantity is less than or equal to 10 kg, or, subject to Special Provision SP 85 or 86 and the quantity is less than or equal to 1000 articles (note: this is number of articles, not mass), Class 1.4 (except Class 1.4S) is 1000 kg or less, Class 6.1 and are not required to comply with Special Provision 23, Class 6.1 but are not an inhalation hazard and are not listed in Special Provision 23. capacity of each cylinder is greater than 225 L, are interconnected through a piping arrangement, and, are permanently mounted on a structural frame for transport, Class 6.1 for exposure to other routes (not an inhalation hazard)and are not listed in Special Provision 23, Class 6.1, Toxic Substances due to inhalation toxicity, Are dangerous goods subject to Special Provision 23. Other safety marks are shown in Table 2 in this document (below). However, if these two substances were mixed, the resulting mixture of these two products would still be regulated as a dangerous good. A placard is used for a large means of containment whose capacity is more than 450 L. The marks for safety for each TDG class are shown in the OSH Answers document Transportation of Dangerous Goods (TDG) - 9 Classes. Ark. to indicate that the flash point is a closed cup test value (e.g., 27 clesius degrees c.c.). Wastes: If the product is a waste, then the shipping name is either preceded or followed by the word waste. Where different hazardous materials in limited quantities are packed together in the same outer packaging, when a gross mass is indicated Column 4 of 173.27 Table 3, the net quantity of each hazardous material must be shown in addition to the gross mass of the completed package. Once the material has been tested at a laboratory, the test results are compared to the classification criteria in Part 2. When the dangerous goods safety marks are, primary class label and each subsidiary class label for each of the dangerous goods, as well as the shipping name and UN number, must be displayed on the overpack, the word overpack is required on at least one side for overpacks with capacity less than 1.8 m3 (64 cubic feet), the words overpack on at least two opposite, required to display subsidiary hazard class placard. Other dangerous goods safety marks that may be required for a shipment of dangerous goods are summarized in Table 2 below. Appendix E: Schedule 2 - List of Dangerous Goods Consequently, the compatibility group will be already assigned by the Natural Resources Canada. Code 5-3-25.4 - 410 IAC 5-3-25.4 - Advance notice of transport of nuclear waste, Kan. Admin. Transportation of Dangerous Goods (TDG) - 9 Classes, TDG "Special Case and Special Provision Exemptions. Are the classifications for other modes or international shipments the same? "R}~Q:~pgg'"l/O:OV~ @zo7g;)K;=d'}z8}7w7?Iuw?w~ikK^^'d4k;g_u_LOC6($uiz["Dw#b{ogw~0B"ty'{~Oi"v?`"DqXmImPiww#R{;?j}J3]0{ ?>]|YlbE#SsBsz/E":}NCg7ON2P5N}s/w?9LO?zZ^/1BWu~N"r~!P;1FAS*:hzQHo _+3l3E6FAsmH}]fwcxoCcbb,!7cTvt{o&h: foC"uF2c;&4m;vx?=8 ga ` !%6M`Wn-@lM;#={CSaW+r:&|gB7/ndJlXqFxs1}n]N:=jd#]5$b{9NF">OL_7!y;3~*cQlCek4o6 eeGn:9P_mO}W'^q7{X,V{TFi8Qj eg/od{QVg{*Ky3n_0ht vv@9g;OkRz~w}79!^C:[7C .{;T/tUOB9x|]\;Q7W{!~uhM Always check the TDG Act and Regulations to ensure compliance. A label is used for a small means of containment whose capacity is 450 L or less. The most appropriate designation for the dangerous goods must be selected based on each class, UN number and packing group established per the classification requirements of clause 4.5. When test results and the hazard class criteria are compared, there are three possible conclusions: a) The laboratory test results show the product does not meet any of the criteria for the hazard classes. They will be used to label dangerous goods. The three forms }qI;<>q2=4s; y5J The Proper Shipping Name shall be supplemented with "STABILIZED"; Mixtures or Solutions: Dangerous Goods Classes and Symbols Indication of the packaging specification number (1H1) may be included in the description of the package (for example, 12 1H1 drums or 12 drums (UN 1A1)). Developed by Mercury and its joint venture company Cummins MerCruiser Diesel (CMD), the Zeus drive is a dual However, if the product's name is not listed in Schedule 1 or 3, then the product must be tested at a laboratory. Corrosives 9. In this article, we will share with you some rules you need to follow when choosing UN numbers and proper shipping names. Perchlorates. (1) The total quantity of the material covered by one description must appear before or after, or both before and after, the description required and authorized by this subpart. sponsor this page to leave your contact info on this page.. By using the information provided in the HMT, you can correctly describe the hazardous materials shipment. If a small means of containment is placed inside another, and the outer container is not opened during loading, transport or unloading, the label is required only on the outer small means of containment. ), 4. This requirement is outlined in Part 5 of the TDG Regulations. The primary class of dangerous goods is the hazard class that poses the highest hazard and takes precedence over any other class posing a lower hazard. This mark is required when shipments meet the excepted quantity exemption. This document may be: The proof of classification must include the following information: The TDG Directorate keeps alist of laboratoriesthat provide dangerous goods analysis and classification. :/z6+^OHfamwfe~:[NF/{^f&onaR;`N=EIM&&G* mG6[0b@,d a|};>Swhl_qmlc/ZI/*_:y,B.y'WvPkzZ. Generally, the shipping name should be selected in the following hierarchical order: 1. See the images below for examples of how to place the dangerous goods placards on large means of containments such as a highway tank (Figure 3), and compartmentalized means of containment (Figure 4). ;imX'1r9-Ttomh1!u~cSyK,v=d+2Cl>AmY\t%v|a&H%dl>; CbtgspL4nj(|c24O?DY_L[;!/aw=yAcC)fMZEnti ]~Mal};jv|y{D}odxh*ap-UDw,EY"h7!G07znrn83Qa=Xre:NWMg]3|u`gho7Ay0Cgh!7tf16+OIXe"m>GNkhhu&.7f{,M` =WaJ`I{W2O_eBX;96$ljWt8 For example, both gasoline and diesel are listed by their name in Schedule 1. Note: The NA numbers in the 49 CFR are not permitted in Canada.
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